新元古代—寒武纪硫同位素异常事件(Yudomski事件)的起源与结束          下载免费PDF全文

张智礼  孟凡巍  倪培  李慧莉  卓勤功 《盐湖研究》2020,28(4):22-28

新元古代晚期—寒武纪早期是地球历史演化的关键时期,整个生物圈、大气圈和水圈在此期间都发生了巨大的变化,海水成分在其间也发生了明显的变化。而石盐流体包裹体恰恰记录了该时段海水主要离子成分的转变:海水成分从新元古代晚期的“文石海”,快速转化为寒武纪的“方解石海”；同时海水中的碳、锶、硫同位素都发生了剧烈的改变,其中海水硫酸根的硫同位素从新元古代冰期前的20‰左右,迅速升高到新元古代冰期后的35‰左右,甚至可以到45‰,海相蒸发岩沉积中的硫酸盐沉积(主要是石膏、硬石膏)则直接记录了当时海水中硫酸根的硫同位素变化。现有研究表明,新元古代晚期——寒武纪时期的海相蒸发岩沉积记录了当时海洋中存在着地质历史时期最大的硫同位素异常,即“Yudomski事件”。塔里木盆地的寒武纪早期、中期蒸发岩记录了“Yudomski事件”的硫同位素异常高值(35‰左右,甚至更高),表明这一起源于新元古代晚期的同位素异常事件持续到了寒武纪的早期和中期；塔里木盆地奥陶纪早期的蒸发岩、鄂尔多斯盆地奥陶纪中期蒸发岩和美国Williston盆地奥陶纪晚期地层的蒸发岩的硫同位素数据相似,都在+25‰左右则记录了较低的海洋硫同位素值,表明起源于新元古代冰期之后的“Yudomski事件”的硫同位素异常,持续到了寒武纪的中期,而结束于寒武纪的晚期。  相似文献   

Wintertime rates of net primary production and nitrate and ammonium uptake in the southern Benguela upwelling system     

RF Flynn  JM Burger  K Pillay 《African Journal of Marine Science》2018,40(3):253-266

The elevated levels of primary productivity associated with eastern boundary currents are driven by nutrient- rich waters upwelled from depth, such that these regions are typically characterised by high rates of nitrate-fuelled phytoplankton growth. Production studies from the southern Benguela upwelling system (SBUS) tend to be biased towards the summer upwelling season, yet winter data are required to compute annual budgets and understand seasonal variability. Net primary production (NPP) and nitrate and ammonium uptake were measured concurrently at six stations in the SBUS in early winter. While euphotic zone NPP was highest at the stations nearest to the coast and declined with distance from the shore, a greater proportion was potentially exportable from open-ocean surface waters, as indicated by the higher specific nitrate uptake rates and f-ratios (ratio of nitrate uptake to total nitrogen consumption) at the stations located off the continental shelf. Near the coast, phytoplankton growth was predominantly supported by ammonium despite the high ambient nitrate concentrations. Along with ammonium concentrations as high as 3.6 µmol l^–1, this strongly suggests that nitrate uptake in the inshore SBUS, and by extension carbon drawdown, is inhibited by ammonium, at least in winter, although this has also been hypothesised for the summer.  相似文献   

南海北部冷泉区深水珊瑚的发现及其特征     

陈忠  莫爱彬  赵美霞  仲义  颜文 《热带海洋学报》2018,37(1):64-71

冷水珊瑚也称为深水珊瑚, 在生物多样性、生态资源和科研价值等方面具有重要意义。文章对采自南海北部冷泉区的冷水珊瑚骨骼碎屑进行测定, 鉴定出冷水珊瑚2个种(Crispatotrochus sp.1和Crispatotrochus sp.2), 以及4个属[Balanophyllia (Balanophyllia)、Balanophyllia (Eupsammia)、Lochmaeotrochus和Enallopsammia]。测定的冷水珊瑚的δ¹³C为-7.36‰~-1.15‰, δ¹⁸O为-1.38‰~3.67‰, 与全球冷水珊瑚碳氧同位素组成相似, 但明显不同于南海暖水珊瑚、冷泉碳酸盐岩及低温热液成因碳酸盐岩的碳氧同位素组成。  相似文献   

基于碳、氮稳定同位素的雅浦海沟底栖生物食物来源和营养级初探     

郭承秧  杨志  陈建芳  郑豪  张东声  冉莉华  王春生  鹿博  陈倩娜 《海洋学报》2018,40(10):51-60

为了分析雅浦海沟中底栖生物群落的食物来源和营养级，本研究分析了雅浦海沟真光层中浮游植物和浮游动物、海底沉积物和巨型底栖生物（海绵、海参、海蛇尾、海星、海葵和钩虾）中的碳、氮稳定同位素组成。研究发现雅浦海沟真光层中的浮游植物和浮游动物δ13C值[（-22.8±0.4）‰和（-21.8±0.8）‰]和δ15N值[（5.4±0.4）‰和（6.8±0.2）‰]与巨型底栖生物的δ13C值（-20.1‰~-16.8‰）和δ15N值（11.9‰~17.9‰）的差异超过了一个营养级，表明作为底栖生物的初始食物来源的浮游植物和浮游动物在向下输送的过程中经历了食物链传递和细菌的降解。巨型底栖生物的δ15N和δ13C值之间无显著的相关性，此外不同物种之间营养级也存在明显差异，表现为海绵的营养级相对较高（3.4~4.7），海参（3.3~3.6）、海蛇尾（3.4~3.5）和海星（3.2~3.7）的营养级较为接近，钩虾（2.9~3.3）和海葵（3.1）的营养级则相对略低，反映了底栖生物不同物种之间食物来源的多样化。  相似文献   

Seasonal dynamics of water and nutrient fluxes in an agricultural peatland          下载免费PDF全文

Casey D. Kennedy  Nickolas Alverson  Peter Jeranyama  Carolyn DeMoranville 《水文研究》2018,32(6):698-712

The American cranberry (Vaccinium macrocarpon Ait.) is an important part of the cultural heritage and economy of Southeastern Massachusetts, yet water quality concerns and wetland protection laws challenge its commercial production. Here, we report inputs and outputs of water, nitrogen (N), and phosphorus (P) for a 2.12‐ha cranberry bed over a 2‐year period from 2013 to 2015. Water‐budget analysis indicated that precipitation contributed 40%, floodwater 37%, irrigation 15%, and groundwater 8% of water inputs to the cranberry bed. Minor annual variation in surface water discharge (~90 mm·year^?1 or 3%) contrasted with large decreases in net (= outputs ? inputs) nutrient export, from 16.2 to 9.1 kg N·ha^?1·year^?1 for total (dissolved + suspended particulate) nitrogen (TN) and from 3.34 to 1.47 kg P·ha^?1·year^?1 for total phosphorus (TP) between Years 1 and 2. Annual variation in net TN and TP export was tied to decreases in spring and summer nutrient export and controlled by the combined effects of fertilizer management, soil biogeochemistry, and hydrology. The relatively high spring TN export in Year 1 was associated with coincident increases in soil temperature and rainfall. A second factor was the timing of fertilizer application, which occurred 1 day prior to a major summer storm (i.e., third largest daily rainfall since 1926) and was responsible for up to 15% and 9% of the Year 1 TN and TP export, respectively. Nutrient budgets, which balanced water and fertilizer inputs with water, fruit, and vegetative outputs, were consistent with the burial of 21.6 kg N·ha^?1·year^?1 and 7.27 kg P·ha^?1·year^?1. Field measurements indicated that burial would increase TN and TP in the shallow (0–5 cm) rooting zone by 14% and 6%, respectively, which seemed plausible based on the relatively young age of the bed (4–5 years) and new root growth patterns in Vaccinium plants.  相似文献   

碳氮稳定同位素比值在潮间带大型底栖动物组织间差异性研究   总被引：1，自引：1，他引：0  

刘博  陈琳琳  李宝泉  侯西勇  冯光海  李晓炜  李秉钧  王玉珏 《海洋学报》2019,41(4):74-82

近年来，稳定同位素技术已被广泛应用于食物网研究中。然而，生物样品取样部位对食物网构建的影响的研究相对少见。大型底栖动物作为潮间带食物网的重要组成部分，在食物网研究中有必要对其采样部位进行统一，以增加研究结果的准确性及可比较性。本研究选取黄河三角洲和烟台潮间带10种代表性的大型底栖动物，比较δ13C和δ15N在不同采样部位中的差异。结果显示，对于大多数底栖动物而言，采样部位将直接影响到δ13C和δ15N的测定结果。当底栖动物作为摄食者，需分析其食性和营养级时，应统一采用肌肉组织，如贝类的闭壳肌或足部肌肉，蟹类的鳌足肌肉，鱼类的背部肌肉；当底栖动物作为被摄食者，需分析次级消费者的食性和营养级时，除多毛类采用去除消化道内容物的体壁外，其他种类应选取整体（难以被消化的组织除外），如贝类的软体部，蟹类肌肉与鳃等的混合组织。  相似文献   

柴达木盆地碱山深钻的硼同位素地球化学特征          下载免费PDF全文

卢胜城  韩文霞  韩凤清  马云麒  吕爽 《盐湖研究》2020,28(1):60-68

沉积物硼(B)同位素组成可以反映其地质成因及经历的地质过程,因此在许多领域的研究中都有较为广泛的应用。通过对位于柴达木盆地碱山背斜顶部的SG-1b钻孔沉积物(7.3～1.6 Ma)水溶组分的B同位素研究,发现钻孔沉积物B含量在38.55～172.3μg/g之间,平均含量为87.6μg/g;δ~(11)B值的变化范围在3.61‰～16.26‰之间,平均值为10.65‰,B含量与δ~(11)B值具有一定的正相关关系。进一步分析表明,受到碱山背斜构造隆升以及晚新生代以来气候干旱化的影响,柴西古湖逐渐咸化萎缩,沉积环境以及碳酸盐含量、粘土矿物含量及其矿物组合等也在发生变化,B含量和δ~(11)B值自钻孔底部向上的逐步增加以及后期的急剧增加,与水溶离子含量以及矿物和粒度等的变化一致,这说明柴达木盆地晚中新世以来湖泊沉积物的B含量和δ~(11)B值可以很好地反映研究区气候和湖水的演化过程,共同指示了研究区自7.3 Ma以来气候的持续干旱化和湖水盐度的逐步增加,以及3.3Ma以来干旱化和湖水浓缩过程的加剧。  相似文献   

GEOCHEMISTRY     

《Abstract of Chinese Geological Literature》2014,(3)

正20141357 Guo Tao(School of Mathematics and Science,Shijiazhuang University of Economics,Shijiazhuang 050031,China);Hu Jiawen Assessment on the New Pressure-Volume-Temperature(PVT) Data of Supercritical Water(Geological Journal of China Universities,ISSN1006-7493,CN32-1440/P,19(3),2013,p.447-455,9 illus.,3 tables,32 refs.)Key words:supercritical fluids  相似文献   

Calibration of oxygen isotope fractionation and calcite-corundum thermometry in emery at Naxos,Greece     

Rachelle B. Turnier  Yaron Katzir  Kouki Kitajima  Ian J. Orland  Michael J. Spicuzza  John W. Valley 《Journal of Metamorphic Geology》2020,38(1):53-70

Corundum (Crn), including sapphire, occurs in emery pods surrounded by marble on the island of Naxos, Greece. The emery formed from bauxite deposited in karst that was metamorphosed to 400–700°C at 20–15 Ma. Many of these rocks initially appeared well suited for refractory accessory mineral (RAM) thermometry, which uses oxygen isotope fractionation between a RAM – corundum – and a modally dominant phase with faster diffusion of oxygen – calcite (Cc) – to determine peak metamorphic temperatures. However, previous attempts at oxygen isotope thermometry were confounded by highly variable fractionations (Δ¹⁸O) measured at mm-scale and the uncertain calibration of Δ¹⁸O(Cc-Crn) versus temperature. Secondary ion mass spectrometry (SIMS) permits in situ analysis of δ¹⁸O in corundum and calcite at the 10-μm scale in adjacent grains where textures suggest peak metamorphic equilibrium was attained. SIMS analyses of adjacent mineral pairs in eight rocks yield values of Δ(Cc-Crn) that systematically decrease from 7.2 to 2.9‰ at higher metamorphic grade. Pairing these data with independent temperature estimates from mineral isograds yields an empirical calibration of 1,000 lnα(Cc-Crn) = 2.72 ± 0.3 × 10⁶/T² (T in K). The new fractionations (2.7‰ at 1,000 K) are significantly smaller than those calculated from the modified increment method (6.5‰ at 1,000 K; Zheng, Geochimica et Cosmochimica Acta, 1991, 55:2299–2307; Zheng, Mineral Mag, 1994, 58A:1000–1001), which yield unreasonably high temperatures of 630 to 1,140°C when applied to the new Naxos data. The new calibration of Δ(Cc-Crn) can be combined with published fractionations to calculate A-factors for corundum versus a range of 14 other minerals. These new fractionation factors can be used for thermometry or to constrain the genesis of corundum. A compilation of gem corundum δ¹⁸O values shows that many igneous sapphires, including important deposits of basalt-associated sapphire, are mildly elevated in δ¹⁸O relative to the calculated range in equilibrium with mantle values (4.4–5.7‰) and formed from evolved magmas.  相似文献   

中国近海生态环境变化的同位素示踪研究     

陈敏  曾健  杨伟锋 《海洋学报》2018,40(10):32-41

同位素在确定物质来源、指示生物地球化学循环路径、定量生物地球化学过程速率等方面具有独特的优势，本文以近海生态环境变化研究中常用的稳定同位素（13C、15N、18O）和放射性核素（14C、234Th、232Th、230Th、228Th、210Po、210Pb、137Cs、226Ra、228Ra、224Ra、223Ra）为对象，介绍它们在揭示海洋有机质来源、食物网结构、水体缺氧机制、氮循环过程、颗粒动力学、海底地下水输入、有机地球化学过程、沉积年代学等方面的应用，侧重于总结我国近海生态环境研究中同位素示踪取得的进展。伴随着我国经济的发展，近百年来我国近海生态环境也发生了明显的变化，基于同位素示踪揭示的近海富营养化和沉积环境的演变规律表明，我国近海生态环境自20世纪50年代起经历持续的变化，特别是在过去20~30年时间里，近海生态环境的变化尤为剧烈，反映出人类活动是我国近海生态环境变化的主要驱动力。未来需要通过发展新的同位素技术及拓展更广泛的应用，围绕近海海洋生态环境变化的突出问题，重点揭示近海生态环境变化的响应特征、变化速率和作用机制，从而系统地掌握近海生态环境的时空变化规律。  相似文献